Earth Sciences Division (ESD) Department of Energy (DOE) Lawrence Berkeley National Laboratory (LBNL)

Isotopic Measurements

The Center for Isotope Geochemistry (CIG) is a state-of-the-art analytical facility established in 1988 to measure the concentrations and isotopic compositions of elements in rocks, minerals, and fluids in the earth’s crust, atmosphere, and oceans. Research by the Fundamental & Exploratory Research Program of the Earth Sciences Division (ESD) at LBNL that is conducted at this center is directed at finding new ways to use isotopic information to study earth processes, such as long-term climate changes, and at predicting the chemical transport of mantle-derived or deep crustal fluids as they move through the crust.

One of the major problems being studied at CIG is how to estimate fluid-solid reaction rates in natural-groundwater higher-temperature geothermal conditions, particularly as these rates affect mineral dissolution and secondary mineral precipitation. ESD researchers are developing novel ways of estimating reaction rates by using isotopic tracers (primarily strontium, but also uranium and neodymium) to determine solid-fluid exchange rates in various natural situations. Scientists are able to derive the “reaction length,” a parameter that depends on the ratio of isotope transport by diffusion and advection to the reaction rate. The ultimate objective is to understand the microscopic (as well as pore-scale and mesoscale) characteristics of natural systems that have been characterized in terms of “field scale” reaction-rate measures. An intermediate goal is to establish empirically the natural range of fluid-solid reaction rates. Examples are the U-Th/He geochronology of young volcanic rock, understanding and predicting the microbial degradation of chlorinated solvents with carbon isotopes, and using xenon isotopes to study buried waste.

Related Projects and Supporting Activities
  • Integrated Isotope Studies of Geochemical Processes (D. DePaolo)
  • Development of Isotope Techniques for Reservoir and Aquifer Characterization (B. Kennedy)
  • Kinetic Isotope Fractionation by Diffusion in Liquids (J. Christensen)